Lewis structures
We have already seen that valence
electrons are represented by dots in the Lewis description of atoms; in the
same way, lone pairs of electrons in molecules and the shared electron pairs of
covalent bonds may also be represented by pairs of dots.
However, if all the molecular
valence electrons are explicitly shown by dots, larger molecules are tedious to
draw and too complicated to view. Consequently, from now on we shall follow the
simpler convention that the shared electron pair of a covalent bond is
represented by a short line, and that only lone pairs and unpaired valence
electrons are shown as dots.
bond radius is determined from the
atomic separations in the metal. The ionic radius of an element is determined
from measurements on crystals of an ionic compound which contain the element as
monoatomic ions (e.g. Na+, Ca2+, Cl−, and O2–).
Notice from the values in the
table that the sizes (radii) of atoms tend to become smaller on going from left
to the right across a period, and to become larger on going down a group. These
tendencies result first from the increasing positive charge of the nucleus and
its consequent hold on electrons on going from left to right across a period,
and secondly from the expanding valence electron shell of the atom upon
descending a group.
It is very important to be able to
draw correct (simplified) Lewis structures in organic chemistry, especially when
we look at how organic reactions occur (since this involves the redistribution
of valence electrons). Note that all the electrons in almost all stable
molecules and ions are spin paired; a chemical species with an unpaired electron is called a radical and
is usually very reactive.
Example 1
For each of the following
compounds, show the connectivity of the atoms and all valence electrons, then
draw the (simplified) Lewis structure representing covalent bonds (if there are
any) by lines.
(a) NH3
(b) BH3
(c) NaCl
Solution
The neutral N and B atoms have five
and three valence electrons, respectively. The N in ammonia has a full valence
shell (an octet) which includes one lone pair. Boron with just three valence
electrons can form no more than three simple covalent bonds, e.g. with three H
atoms to give the molecule shown, borane. Even then, it still has only six
valence electrons, i.e. an incomplete valence shell. NaCl is an ionic compound.
Guide for drawing correct Lewis structures
The following is a guide for
drawing correct Lewis structures of more complex molecules, with bonding pairs represented
by short lines.
1. First, arrange the atoms of the molecule or ion
according to how they are bonded together; add dots around each atom
corresponding to the number of valence electrons of the neutral atom. Then, add
extra dots according to the negative charge for an anion, or delete dots
according to the positive charge for a cation.
2. As examples, consider Lewis structures of the series
water (H2O), hydroxide ion (HO−), and oxonium ion (H3O+). First, put the atoms
in place with their valence electrons. Then
identify each bond between the O
atom and an H with a (shared) pair of electrons—one from
the O and one from an H. Thirdly, add an extra electron to the O of the anion,
and remove one from the O of the cation.
3. Replace pairs of dots representing shared electron
pairs (covalent bonds) by short lines, and confirm that each non-hydrogen atom
has a valence octet. Here, up to three bonds are possible, and the number of
bonds plus lone pairs is four (i.e. eight valence electrons around the O in
each case).
4. Determine the formal charge for each atom and add the
+ or – value as a superscript to its symbol. The formal charge on an atom is
the number of valence electrons in the neutral atom (before bonding), minus the
number of unshared electrons around the bonded atom, minus the number of
bonding pairs; in abbreviated form, this formula is given by:
Formalcharge =
(valenceelectrons) − (unsharedelectrons) − (bondingspairs)
Example 2
Calculation of the formal charge
on the oxygen atom in H2O, HO−, and H3O+:
Methanol CH3OH
(i) Arrange all the constituent atoms
and put in dots for valence electrons
(for the sake of clarity, numbers of valence electrons are summarized on the
left); (ii) identify pairs of electrons which correspond to covalent bonds and
replace each by a line (this gives the Lewis structure); confirm that all
non-hydrogen atoms have valence octets;
(iii) calculate the formal charges
(equal to zero).
Methanal CH2O
Proceeding as above, we find that
making one bond between C and O leaves one unpaired electron on each of C and
O. These electrons are paired to form a second bond between C and O to give the
C=O double bond; both C and O now have full valence octets. Formal charges are
all zero.
Boron trifluoride BF3
This molecule contains only three
bonds since B has only three valence electrons. It follows that B in BF3 has
only six electrons whereas all three F atoms have full valence octets.
Ammonium ion NH+4
This ion has a positive charge so,
according to step (1) in the protocol for drawing Lewis structures described in
Subsection 1.3.1, one electron is deleted from the normal number of valence electrons for N.
Calculation of the formal charge on the
N shows that it is +1 even though the N has a complete valence octet.
Methyl anion CH3−
This ion has a negative charge so
one extra electron is put onto the C. Bond lines are drawn and the formal
charge is calculated: with an unshared electron pair on the C, the formal
charge is –1.
Ethanoate anion CH3CO−2
One extra electron is added to one
of the O atoms for this anion. In the structure with only single bonds, the O
carrying the extra electron has an octet, but the other O has only seven
electrons. The C to which it is bonded also has an unpaired electron, however,
so a C=O double bond can be formed and both of these atoms then achieve
complete octets. When the procedure for calculating formal charge is carried
out on the singly bonded O atom with the extra electron, it turns out to be –1;
all other formal charges are zero.
In the above, the extra electron
was arbitrarily put on one of the O atoms, and we obtained Lewis structure 1a
below. We could equally well have chosen the other O, in which case we would
have finished up with Lewis structures 1b; both 1a and 1b are legitimate Lewis
structures for ethanoate anion. The significance of this will be discussed in
the next section.
Nitromethane CH3NO2
Finally, we construct the Lewis
structure of nitromethane. The connection of atoms in the nitro group (NO2) may
not be familiar yet, but it is shown below. Each of the two O atoms in the
singly bonded structure has seven electrons, so each has an unpaired electron
(all other atoms have complete valence shells). A bond between the two O atoms
would satisfy the valence requirements but would give a three-membered ring
which would be very strained and hence unstable.
Alternatively, if we tried to make
two N=O (double) bonds using another two electrons on N, the result would be an
impossible structure with 10 valence electrons on the N. Thirdly, if one
electron is transferred from the N lone pair to one O, the unpaired electron
left on the N can form a second bond to the other O. By this procedure, the
valence requirements of all atoms are satisfied and the outcome is the
reasonable Lewis structure shown; it simply needs the addition of formal
charges.
The nitrogen has four bonds and no
lone pairs, so its formal charge by eqn 1.10 is (5 − 4) =+1. The value for the
singly-bonded O is (6 – 6 – 1) = –1 since it has 6 unshared electrons (three
lone pairs) and one bond. The other (double-bonded) O has four unshared
electrons and two bonds so the formal charge on this atom is 6 − 4 − 2 = 0.
This Lewis structure, therefore, involves charge separation even though the
molecule is neutral overall.
The bonding shown for nitromethane
is similar to that within the ethanoate ion described above. One of the two O
atoms is double bonded and the singly bonded one bears a formal negative
charge, as shown in structure 2a. And just as in the case of ethanoate, the O
atoms could be switched around to give an alternative equivalent Lewis
structure, 2b.
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